首页> 外文OA文献 >Phase diagrams of charged colloidal rods: can a uniaxial charge distribution break chiral symmetry?
【2h】

Phase diagrams of charged colloidal rods: can a uniaxial charge distribution break chiral symmetry?

机译:带电胶体棒的相图:可以是单轴电荷   分布断裂手征对称?

代理获取
本网站仅为用户提供外文OA文献查询和代理获取服务,本网站没有原文。下单后我们将采用程序或人工为您竭诚获取高质量的原文,但由于OA文献来源多样且变更频繁,仍可能出现获取不到、文献不完整或与标题不符等情况,如果获取不到我们将提供退款服务。请知悉。
获取外文期刊封面目录资料

摘要

We construct phase diagrams for charged rodlike colloids within thesecond-virial approximation as a function of rod concentration, saltconcentration, and colloidal charge. Besides the expected isotropic-nematictransition, we also find parameter regimes with a coexistence between a nematicand a second, more highly aligned nematic phase including anisotropic-nematic-nematic triple point and a nematic-nematic critical point,which can all be explained in terms of the twisting effect. We compute theFrank elastic constants to see if the twist elastic constant can becomenegative, which would indicate the possibility of a cholesteric phasespontaneously forming. Although the twisting effect reduces the twist elasticconstant, we find that it always remains positive. In addition, we find thatfor finite aspect-ratio rods the twist elastic constant is also alwayspositive, such that there is no evidence of chiral symmetry breaking due to auniaxial charge distribution.
机译:我们构建第二病毒近似内带电的棒状胶体的相图,该相图是棒浓度,盐浓度和胶体电荷的函数。除了预期的各向同性向列相变外,我们还发现了向列相与第二个高度对齐的向列相共存的参数体系,包括各向异性向列向列三点和向列向列临界点,所有这些都可以用扭曲的效果。我们计算弗兰克弹性常数以查看扭曲弹性常数是否可以变为负数,这将表明胆甾相自发形成的可能性。尽管扭曲效果降低了扭曲弹性常数,但我们发现它始终保持正值。此外,我们发现对于有限长宽比的杆,扭转弹性常数也始终是正的,因此没有证据表明由于单轴电荷分布而导致手性对称性破坏。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
代理获取

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号